Size-exclusion chromatography (SEC) of branched polymers and polysaccharides

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Size-exclusion chromatography (SEC) of branched polymers and polysaccharides

Branched polymers are among the most important polymers, ranging from polyolefins to polysaccharides. Branching plays a key role in the chain dynamics. It is thus very important for application properties such as mechanical and adhesive properties and digestibility. It also plays a key role in viscous properties, and thus in the mechanism of the separation of these polymers in size-exclusion ch...

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Size Exclusion Chromatography of Polymers

In the characterization of polymers, size-exclusion chromatography (SEC) has become a standard technique for determining molar mass averages andmolar mass distributions (MMD) of polymers. The principle of SEC is easily understood: owing to limited accessability of the pore volume within the particles of the column packing, polymer molecules are separated according to their hydrodynamic volumes,...

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Size-Exclusion Chromatography of Polysaccharides with Pulsed Amperometric Detection (PAD)

INTRODUCTION Size-exclusion chromatography is used in carbohydrate research to determine molecular weight distributions of polysaccharides. A variety of detection methods have been used, among them viscometry, lowangle laser light scattering (LALLS), refractive index, ultraviolet/visible absorbance, fluorescence, and precision differential refractometry coupled with ultraviolet detection.This a...

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Size-Exclusion Chromatography of Polysaccharides with Pulsed Amperometric Detection (PAD)

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ژورنال

عنوان ژورنال: Analytical and Bioanalytical Chemistry

سال: 2010

ISSN: 1618-2642,1618-2650

DOI: 10.1007/s00216-010-4221-7